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Coexistence of Two Different Distorted Octahedral [MnF(6)](3−) Sites in K(3)[MnF(6)]: Manifestation in Spectroscopy and Magnetism
As a consequence of the static Jahn‐Teller effect of the (5)E ground state of Mn(III) in cubic structures with octahedral parent geometries, their octahedral coordination spheres become distorted. In the case of six fluorido ligands, [MnF(6)](3−) anions with two longer and four shorter Mn−F bonds ma...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362050/ https://www.ncbi.nlm.nih.gov/pubmed/33830547 http://dx.doi.org/10.1002/chem.202005496 |