Understanding Ligand‐Directed Heterogeneous Catalysis: When the Dynamically Changing Nature of the Ligand Layer Controls the Hydrogenation Selectivity

We present a mechanistic study on the formation and dynamic changes of a ligand‐based heterogeneous Pd catalyst for chemoselective hydrogenation of α,β‐unsaturated aldehyde acrolein. Deposition of allyl cyanide as a precursor of a ligand layer renders Pd highly active and close to 100 % selective to...

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Detalles Bibliográficos
Autores principales: Schröder, Carsten, Schmidt, Marvin C., Haugg, Philipp A., Baumann, Ann‐Katrin, Smyczek, Jan, Schauermann, Swetlana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362066/
https://www.ncbi.nlm.nih.gov/pubmed/34008906
http://dx.doi.org/10.1002/anie.202103960

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362066/
https://www.ncbi.nlm.nih.gov/pubmed/34008906
http://dx.doi.org/10.1002/anie.202103960

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