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Understanding Ligand‐Directed Heterogeneous Catalysis: When the Dynamically Changing Nature of the Ligand Layer Controls the Hydrogenation Selectivity
We present a mechanistic study on the formation and dynamic changes of a ligand‐based heterogeneous Pd catalyst for chemoselective hydrogenation of α,β‐unsaturated aldehyde acrolein. Deposition of allyl cyanide as a precursor of a ligand layer renders Pd highly active and close to 100 % selective to...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362066/ https://www.ncbi.nlm.nih.gov/pubmed/34008906 http://dx.doi.org/10.1002/anie.202103960 |