Transition Metal Catalyst‐Free, Base‐Promoted 1,2‐Additions of Polyfluorophenylboronates to Aldehydes and Ketones

A novel protocol for the transition metal‐free 1,2‐addition of polyfluoroaryl boronate esters to aldehydes and ketones is reported, which provides secondary alcohols, tertiary alcohols, and ketones. Control experiments and DFT calculations indicate that both the ortho‐F substituents on the polyfluor...

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Detalles Bibliográficos
Autores principales: Liu, Zhiqiang, Kole, Goutam Kumar, Budiman, Yudha P., Tian, Ya‐Ming, Friedrich, Alexandra, Luo, Xiaoling, Westcott, Stephen A., Radius, Udo, Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362073/
https://www.ncbi.nlm.nih.gov/pubmed/33901332
http://dx.doi.org/10.1002/anie.202103686

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362073/
https://www.ncbi.nlm.nih.gov/pubmed/33901332
http://dx.doi.org/10.1002/anie.202103686

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