Cargando…

Transition Metal Catalyst‐Free, Base‐Promoted 1,2‐Additions of Polyfluorophenylboronates to Aldehydes and Ketones

A novel protocol for the transition metal‐free 1,2‐addition of polyfluoroaryl boronate esters to aldehydes and ketones is reported, which provides secondary alcohols, tertiary alcohols, and ketones. Control experiments and DFT calculations indicate that both the ortho‐F substituents on the polyfluor...

Descripción completa

Detalles Bibliográficos
Autores principales:	Liu, Zhiqiang, Kole, Goutam Kumar, Budiman, Yudha P., Tian, Ya‐Ming, Friedrich, Alexandra, Luo, Xiaoling, Westcott, Stephen A., Radius, Udo, Marder, Todd B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362073/ https://www.ncbi.nlm.nih.gov/pubmed/33901332 http://dx.doi.org/10.1002/anie.202103686

Ejemplares similares

Copper‐Catalyzed Oxidative Cross‐Coupling of Electron‐Deficient Polyfluorophenylboronate Esters with Terminal Alkynes
por: Liu, Zhiqiang, et al.
Publicado: (2020)

Base‐Free Pd‐Catalyzed C−Cl Borylation of Fluorinated Aryl Chlorides
por: Budiman, Yudha P., et al.
Publicado: (2021)

Selective, Transition Metal‐free 1,2‐Diboration of Alkyl Halides, Tosylates, and Alcohols
por: Huang, Mingming, et al.
Publicado: (2022)

Ni‐Catalyzed Borylation of Aryl Sulfoxides
por: Huang, Mingming, et al.
Publicado: (2021)

Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
por: Zhang, Guoqi, et al.
Publicado: (2022)

Base‐Mediated Radical Borylation of Alkyl Sulfones
por: Huang, Mingming, et al.
Publicado: (2021)

Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones
por: Shen, Hao-Yu, et al.
Publicado: (2007)

A Green Approach for Allylations of Aldehydes and Ketones: Combining Allylborate, Mechanochemistry and Lanthanide Catalyst
por: de Souza, Viviane P., et al.
Publicado: (2016)

Chemoselective Electrochemical Hydrogenation of Ketones and Aldehydes with a Well‐Defined Base‐Metal Catalyst
por: Fokin, Igor, et al.
Publicado: (2020)

N‐Heterocyclic Silylenes as Ligands in Transition Metal Carbonyl Chemistry: Nature of Their Bonding and Supposed Innocence
por: Krahfuß, Mirjam J., et al.
Publicado: (2020)

Incorporating heterogeneous lacunary Keggin anions as efficient catalysts for solvent-free cyanosilylation of aldehydes and ketones
por: Malmir, Masoume, et al.
Publicado: (2022)

Regio‐ and Stereoselective Synthesis of 1,1‐Diborylalkenes via Brønsted Base‐Catalyzed Mixed Diboration of Alkynyl Esters and Amides with BpinBdan
por: Liu, Xiaocui, et al.
Publicado: (2020)

Two-Carbon Homologation of Aldehydes and Ketones to α,β-Unsaturated Aldehydes
por: Petroski, Richard J., et al.
Publicado: (2011)

Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones
por: Matsukawa, Satoru, et al.
Publicado: (2009)

Highly selective and robust single-atom catalyst Ru(1)/NC for reductive amination of aldehydes/ketones
por: Qi, Haifeng, et al.
Publicado: (2021)

Nickel boryl complexes and nickel-catalyzed alkyne borylation
por: Tendera, Lukas, et al.
Publicado: (2023)

Silyl Anion Initiated Hydroboration of Aldehydes and Ketones
por: Stanford, Martin W., et al.
Publicado: (2020)

Activity and stability studies of H-transfer reduction reactions of aldehydes and ketones over aluminium isopropoxide heterogenised catalysts
por: Muhammad, Atika, et al.
Publicado: (2022)

Directed Lithiation of Protected 4-Chloropyrrolopyrimidine: Addition to Aldehydes and Ketones Aided by Bis(2-dimethylaminoethyl)ether
por: Bjørnstad, Frithjof, et al.
Publicado: (2023)

STIMULATION OF TARSAL RECEPTORS OF THE BLOWFLY BY ALIPHATIC ALDEHYDES AND KETONES
por: Chadwick, L. E., et al.
Publicado: (1949)

Metal-Free Trifluoromethylation of Aromatic and Heteroaromatic Aldehydes and Ketones
por: Qiao, Yupu, et al.
Publicado: (2014)

Homologation of aryl ketones to long-chain ketones and aldehydes via C–C bond cleavage
por: Wang, Xing, et al.
Publicado: (2022)

Cerium-photocatalyzed aerobic oxidation of benzylic alcohols to aldehydes and ketones
por: Yedase, Girish Suresh, et al.
Publicado: (2021)

Zn-Catalyzed Regioselective and Chemoselective Reduction of Aldehydes, Ketones and Imines
por: Zhang, Miaomiao, et al.
Publicado: (2022)

Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones
por: Schroeder, Chelsea M., et al.
Publicado: (2023)

Cyano-borrowing reaction: nickel-catalyzed direct conversion of cyanohydrins and aldehydes/ketones to β-cyano ketone
por: Li, Zhao-Feng, et al.
Publicado: (2019)

Formation of Aldehyde and Ketone Compounds during Production and Storage of Milk Powder
por: Li, Yanhua, et al.
Publicado: (2012)

Ketones and aldehydes as alkyl radical equivalents for C─H functionalization of heteroarenes
por: Dong, Jianyang, et al.
Publicado: (2019)

General Synthesis of Secondary Alkylamines by Reductive Alkylation of Nitriles by Aldehydes and Ketones
por: Schönauer, Timon, et al.
Publicado: (2020)

Aldehydes and ketones in pyrolysis oil: analytical determination and their role in the aging process
por: Baehr, Clarissa, et al.
Publicado: (2022)

Chemoselective Decarboxylative Oxygenation of Carboxylic Acids To Access Ketones, Aldehydes, and Peroxides
por: Guan, Renpeng, et al.
Publicado: (2023)

Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl(2).4H(2)O as an easily accessible and efficient catalyst
por: Ontivero, Melina C., et al.
Publicado: (2021)

Molecular characterization of aldehydes and ketones in particle phase of mainstream and sidestream cigarette smoke
por: Chen, Xiu, et al.
Publicado: (2019)

Alkynes as Synthetic Equivalents of Ketones and Aldehydes: A Hidden Entry into Carbonyl Chemistry
por: Alabugin, Igor V., et al.
Publicado: (2019)

Photocatalytic Barbier reaction – visible-light induced allylation and benzylation of aldehydes and ketones
por: Berger, Anna Lucia, et al.
Publicado: (2018)

Aldehydes and ketones influence reactivity and selectivity in nickel-catalysed Suzuki–Miyaura reactions
por: Cooper, Alasdair K., et al.
Publicado: (2020)

Pincer‐Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide
por: Liu, Lingyu, et al.
Publicado: (2021)

Coinage Metal-Catalyzed Asymmetric Reactions of ortho-Alkynylaryl and Heteroaryl Aldehydes and Ketones
por: Melot, Romain, et al.
Publicado: (2022)

Continuous-flow hydration–condensation reaction: Synthesis of α,β-unsaturated ketones from alkynes and aldehydes by using a heterogeneous solid acid catalyst
por: Rueping, Magnus, et al.
Publicado: (2011)

Evidence for an enolate mechanism in the asymmetric Michael reaction of α,β-unsaturated aldehydes and ketones via a hybrid system of two secondary amine catalysts
por: Umekubo, Nariyoshi, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_erji9eko0irtp1tpae9vcujivo