CeCl(3)/n‐BuLi: Unraveling Imamoto's Organocerium Reagent

CeCl(3)(thf) reacts at low temperatures with MeLi, t‐BuLi, and n‐BuLi to isolable organocerium complexes. Solvent‐dependent extensive n‐BuLi dissociation is revealed by (7)Li NMR spectroscopy, suggesting “Ce(n‐Bu)(3)(thf)(x)” or solvent‐separated ion pairs like “[Li(thf)(4)][Ce(n‐Bu)(4)(thf)(y)]” as...

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Detalles Bibliográficos
Autores principales: Berger, Tassilo, Lebon, Jakob, Maichle‐Mössmer, Cäcilia, Anwander, Reiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362106/
https://www.ncbi.nlm.nih.gov/pubmed/33905590
http://dx.doi.org/10.1002/anie.202103889

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362106/
https://www.ncbi.nlm.nih.gov/pubmed/33905590
http://dx.doi.org/10.1002/anie.202103889

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