Cargando…

CeCl(3)/n‐BuLi: Unraveling Imamoto's Organocerium Reagent

CeCl(3)(thf) reacts at low temperatures with MeLi, t‐BuLi, and n‐BuLi to isolable organocerium complexes. Solvent‐dependent extensive n‐BuLi dissociation is revealed by (7)Li NMR spectroscopy, suggesting “Ce(n‐Bu)(3)(thf)(x)” or solvent‐separated ion pairs like “[Li(thf)(4)][Ce(n‐Bu)(4)(thf)(y)]” as...

Descripción completa

Detalles Bibliográficos
Autores principales:	Berger, Tassilo, Lebon, Jakob, Maichle‐Mössmer, Cäcilia, Anwander, Reiner
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362106/ https://www.ncbi.nlm.nih.gov/pubmed/33905590 http://dx.doi.org/10.1002/anie.202103889

Ejemplares similares

Beyond Takai's Olefination Reagent: Persistent Dehalogenation Emerges in a Chromium(III)‐μ(3)‐Methylidyne Complex
por: Trzmiel, Simon, et al.
Publicado: (2021)

Schlenk's Legacy—Methyllithium Put under Close Scrutiny
por: Lebon, Jakob, et al.
Publicado: (2022)

Effective and Reversible Carbon Dioxide Insertion into Cerium Pyrazolates
por: Bayer, Uwe, et al.
Publicado: (2020)

Effect of Substituents of Cerium Pyrazolates and Pyrrolates on Carbon Dioxide Activation
por: Bayer, Uwe, et al.
Publicado: (2021)

Cerium–quinone redox couples put under scrutiny
por: Bayer, Uwe, et al.
Publicado: (2020)

[(CH(3))Al(CH(2))](12): Methylaluminomethylene (MAM‐12)
por: Spiridopoulos, Georgios, et al.
Publicado: (2022)

Potential Precursors for Terminal Methylidene Rare‐Earth‐Metal Complexes Supported by a Superbulky Tris(pyrazolyl)borato Ligand
por: Birkelbach, Verena M., et al.
Publicado: (2019)

Molecular Signatures of Reduced Nerve Toxicity by CeCl(3) in Phoxim-exposed Silkworm Brains
por: Wang, Binbin, et al.
Publicado: (2015)

Data on the identification of isoprene and Styrene triblock copolymers with difunctional t-BuLi initiator
por: Lee, Pin-Chen, et al.
Publicado: (2020)

C–H-Bond Activation and Isoprene Polymerization Studies Applying Pentamethylcyclopentadienyl-Supported Rare-Earth-Metal Bis(Tetramethylaluminate) and Dimethyl Complexes
por: Hollfelder, Christoph O., et al.
Publicado: (2019)

Molecular Ln(III)−H−E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb)
por: Widemann, Max, et al.
Publicado: (2022)

Nanoscale Organolanthanum Clusters: Nuclearity‐Directing Role of Cyclopentadienyl and Halogenido Ligands
por: Buschmann, Dennis A., et al.
Publicado: (2020)

Ilyen fiatal? Szülinapi buli az Internet tiszteletére
Publicado: (2009)

D-Fructose-based spiro-fused PHOX ligands: synthesis and application in enantioselective allylic alkylation
por: Imrich, Michael R, et al.
Publicado: (2018)

Carbohydrate-Based Chiral Iodoarene Catalysts: A Survey through the Development of an Improved Catalyst Design
por: Imrich, Michael R., et al.
Publicado: (2019)

1,3-Diisopropyl-4,5-dimethylimidazolium benzenesulfonate
por: Sweidan, Kamal, et al.
Publicado: (2011)

Synthesis of the [11]Cyclacene Framework by Repetitive Diels–Alder Cycloadditions
por: Bauer, John B., et al.
Publicado: (2021)

NMR and DFT Studies with a Doubly Labelled (15)N/(6)Li S‐Trifluoromethyl Sulfoximine Reveal Why a Directed ortho‐Lithiation Requires an Excess of n‐BuLi
por: Hédouin, Matthieu, et al.
Publicado: (2022)

Central extracorporeal circulatory life support (cECLS) in selected patients with critical cardiogenic shock
por: Schmack, Leonie, et al.
Publicado: (2023)

Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2)
por: Metzler, Maurice, et al.
Publicado: (2023)

Primary Sulfonamide Synthesis Using the Sulfinylamine Reagent N-Sulfinyl-O-(tert-butyl)hydroxylamine, t-BuONSO
por: Davies, Thomas Q., et al.
Publicado: (2020)

New reductive rearrangement of N-arylindoles triggered by the Grubbs–Stoltz reagent Et(3)SiH/KO(t)Bu
por: Smith, Andrew J., et al.
Publicado: (2020)

Preparation of Polyfunctional Biaryl Derivatives by Cyclolanthanation of 2‐Bromobiaryls and Heterocyclic Analogues Using nBu(2)LaCl⋅4 LiCl
por: Wei, Baosheng, et al.
Publicado: (2019)

Morphological Plasticity of LiCl Clusters Interacting with Grignard Reagent in Tetrahydrofuran
por: de Giovanetti, Marinella, et al.
Publicado: (2023)

Synthesis and Characterization of the Highly Unstable Metalloid Cluster Ag(64)(P(n)Bu(3))(16)Cl(6)
por: Diecke, Maximilian, et al.
Publicado: (2020)

Modulating the Electronic and Solid‐State Structure of Organic Semiconductors by Site‐Specific Substitution: The Case of Tetrafluoropentacenes
por: Geiger, Thomas, et al.
Publicado: (2020)

Synthesis and structural characterization of CO(2)-soluble oxidizers [Bu(4)N]BrO(3) and [Bu(4)N]ClO(3) and their dissolution in cosolvent-modified CO(2) for reservoir applications
por: Hull, Katherine L., et al.
Publicado: (2020)

Comparison of the catalytic activity for the Suzuki–Miyaura reaction of (η(5)-Cp)Pd(IPr)Cl with (η(3)-cinnamyl)Pd(IPr)(Cl) and (η(3)-1-t-Bu-indenyl)Pd(IPr)(Cl)
por: Melvin, Patrick R, et al.
Publicado: (2015)

Radical and Ionic Mechanisms in Rearrangements of o-Tolyl Aryl Ethers and Amines Initiated by the Grubbs–Stoltz Reagent, Et(3)SiH/KO(t)Bu
por: Kolodziejczak, Krystian, et al.
Publicado: (2021)

Correction: Synthesis and structural characterization of CO(2)-soluble oxidizers [Bu(4)N]BrO(3) and [Bu(4)N]ClO(3) and their dissolution in cosolvent-modified CO(2) for reservoir applications
por: Hull, Katherine L., et al.
Publicado: (2021)

Activation of the C[double bond, length as m-dash]P bond in phosphanylphosphaalkenes (C[double bond, length as m-dash]P–P bond system) in the reaction with nucleophilic reagents: MeLi, nBuLi and tBuLi
por: Ziółkowska, Aleksandra, et al.
Publicado: (2022)

Synthesis and characterization of a tert-butyl ester-substituted titanocene dichloride: (t-BuOOC)Cp(2)TiCl(2)
por: McCarthy, Jackson S., et al.
Publicado: (2020)

Unraveling the Roots of Selectivity of Peptide Affinity Reagents for Structurally Similar Ribosomal Inactivating Protein Derivatives
por: Sarkes, Deborah A., et al.
Publicado: (2016)

Unravelling the synthetic and therapeutic aspects of five, six and fused heterocycles using Vilsmeier–Haack reagent
por: Chahal, Mamta, et al.
Publicado: (2023)

Me(3)SiSiMe(2)(O(n)Bu): a disilane reagent for the synthesis of diverse silacycles via Brook- and retro-Brook-type rearrangement
por: Xu, Yankun, et al.
Publicado: (2021)

Probing the Pore of ClC-0 by Substituted Cysteine Accessibility Method Using Methane Thiosulfonate Reagents
por: Lin, Chia-Wei, et al.
Publicado: (2003)

cis-Diastereoselective Synthesis of Spirooxindolo-β-Lactams by Staudinger Cycloaddition with TsCl as Activating Co-reagent
por: Filatov, Vadim E., et al.
Publicado: (2021)

Unraveling the structure and role of Mn and Ce for NOx reduction in application-relevant catalysts
por: Gevers, Lieven E., et al.
Publicado: (2022)

Intermolecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt)
por: Joksch, Markus, et al.
Publicado: (2019)

Studies on metal charge density and band gap characteristics produced by the ((n)BuCp)(2)ZrCl(2) compound and its reaction mechanism
por: Wang, Hai, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_tnbibg3b66atd16qhgtkav9imf