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Controlling Catenation in Germanium(I) Chemistry through Hemilability

We present a novel approach for constructing chains of Group 14 metal atoms linked by unsupported metal–metal bonds that exploits hemilabile ligands to generate unsaturated metal sites. The formation/nature of catenated species (oligo‐dimetallynes) can be controlled by the use of (acidic/basic) “pro...

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Detalles Bibliográficos
Autores principales: Caise, Alexa, Griffin, Liam P., Heilmann, Andreas, McManus, Caitilín, Campos, Jesús, Aldridge, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362110/
https://www.ncbi.nlm.nih.gov/pubmed/33939867
http://dx.doi.org/10.1002/anie.202104643