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Palladium‐Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand‐Assisted Halide Exchange

We report an efficient and broadly applicable palladium‐catalyzed iodination of inexpensive and abundant aryl and vinyl carboxylic acids via in situ activation to the acid chloride and formation of a phosphonium salt. The use of 1‐iodobutane as iodide source in combination with a base and a deoxychl...

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Detalles Bibliográficos
Autores principales: Boehm, Philip, Martini, Tristano, Lee, Yong Ho, Cacherat, Bastien, Morandi, Bill
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362116/
https://www.ncbi.nlm.nih.gov/pubmed/34013616
http://dx.doi.org/10.1002/anie.202103269