High‐Spin Imido Cobalt Complexes with Imidyl Radical Character

We report on the synthesis of a variety of trigonal imido cobalt complexes [Co(NAryl)L(2)](−), (L=N(Dipp)SiMe(3)), Dipp=2,6‐diisopropylphenyl) with very long Co−N(Aryl) bonds of around 1.75 Å. Their electronic structure was interrogated using a variety of physical and spectroscopic methods such as E...

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Detalles Bibliográficos
Autores principales: Reckziegel, Alexander, Kour, Manjinder, Battistella, Beatrice, Mebs, Stefan, Beuthert, Katrin, Berger, Robert, Werncke, C. Gunnar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362137/
https://www.ncbi.nlm.nih.gov/pubmed/33977634
http://dx.doi.org/10.1002/anie.202103841

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362137/
https://www.ncbi.nlm.nih.gov/pubmed/33977634
http://dx.doi.org/10.1002/anie.202103841

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