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High‐Spin Imido Cobalt Complexes with Imidyl Radical Character
We report on the synthesis of a variety of trigonal imido cobalt complexes [Co(NAryl)L(2)](−), (L=N(Dipp)SiMe(3)), Dipp=2,6‐diisopropylphenyl) with very long Co−N(Aryl) bonds of around 1.75 Å. Their electronic structure was interrogated using a variety of physical and spectroscopic methods such as E...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362137/ https://www.ncbi.nlm.nih.gov/pubmed/33977634 http://dx.doi.org/10.1002/anie.202103841 |