Platinum‐Templated Coupling of B=N Units: Synthesis of BNBN Analogues of 1,3‐Dienes and a Butatriene

The 1:2 reaction of [μ‐(dmpm)Pt(nbe)](2) (dmpm=bis(dimethylphosphino)methane, nbe=norbornene) with Cl(2)BNR(SiMe(3)) (R=tBu, SiMe(3)) yields unsymmetrical (N‐aminoboryl)aminoboryl Pt(I) (2) complexes by B−N coupling via ClSiMe(3) elimination. A subsequent intramolecular ClSiMe(3) elimination from th...

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Detalles Bibliográficos
Autores principales: Brunecker, Carina, Arrowsmith, Merle, Fantuzzi, Felipe, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362192/
https://www.ncbi.nlm.nih.gov/pubmed/34036694
http://dx.doi.org/10.1002/anie.202106161

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362192/
https://www.ncbi.nlm.nih.gov/pubmed/34036694
http://dx.doi.org/10.1002/anie.202106161

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