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Analysis of Non‐innocence of Phosphaquinodimethane Ligands when Charge and Aromaticity Come into Play

Several phosphaquinodimethanes and their M(CO)(5) complexes (M=Cr, Mo, W) and model derivatives have been theoretically investigated regarding the quest of non‐innocence. Computed structural and electronic properties of the P‐Me/NH(2) substituted phosphaquinodimethanes and tungsten complexes reveale...

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Detalles Bibliográficos
Autores principales: Junker, Philip, Rey Planells, Alicia, Espinosa Ferao, Arturo, Streubel, Rainer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362198/
https://www.ncbi.nlm.nih.gov/pubmed/33811689
http://dx.doi.org/10.1002/chem.202100420