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Ion correlations drive charge overscreening and heterogeneous nucleation at solid–aqueous electrolyte interfaces

Classical electrical double layer (EDL) models are foundational to the representation of atomistic structure and reactivity at charged interfaces. An important limitation to these models is their dependence on a mean-field approximation that is strictly valid for dilute aqueous solutions. Theoretica...

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Detalles Bibliográficos
Autores principales: Lee, Sang Soo, Koishi, Ayumi, Bourg, Ian C., Fenter, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: National Academy of Sciences 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8364158/
https://www.ncbi.nlm.nih.gov/pubmed/34353907
http://dx.doi.org/10.1073/pnas.2105154118