Stereodynamics of E/Z isomerization in rotaxanes through mechanical shuttling and covalent bond rotation

The mechanical bond has opened a new world for structural and dynamic stereochemistry, which is still largely underexplored and whose significance for various applications is becoming increasingly evident. We demonstrate that designed rearrangements involving both covalent and mechanical bonds can b...

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Detalles Bibliográficos
Autores principales: Corra, Stefano, de Vet, Christiaan, Baroncini, Massimo, Credi, Alberto, Silvi, Serena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8367298/
https://www.ncbi.nlm.nih.gov/pubmed/34435161
http://dx.doi.org/10.1016/j.chempr.2021.04.010

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8367298/
https://www.ncbi.nlm.nih.gov/pubmed/34435161
http://dx.doi.org/10.1016/j.chempr.2021.04.010

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