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Stereodynamics of E/Z isomerization in rotaxanes through mechanical shuttling and covalent bond rotation
The mechanical bond has opened a new world for structural and dynamic stereochemistry, which is still largely underexplored and whose significance for various applications is becoming increasingly evident. We demonstrate that designed rearrangements involving both covalent and mechanical bonds can b...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Elsevier
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8367298/ https://www.ncbi.nlm.nih.gov/pubmed/34435161 http://dx.doi.org/10.1016/j.chempr.2021.04.010 |