Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes

Polyhedral boranes and heteroboranes appear almost exclusively as neutral or anionic species, while the cationic ones are protonated at exoskeletal heteroatoms or they are instable. Here we report the reactivity of 10-vertex closo-dicarbadecaboranes with one or two equivalents of N-heterocyclic carb...

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Detalles Bibliográficos
Autores principales: Vrána, Jan, Holub, Josef, Samsonov, Maksim A., Růžičková, Zdeňka, Cvačka, Josef, McKee, Michael L., Fanfrlík, Jindřich, Hnyk, Drahomír, Růžička, Aleš
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8371172/
https://www.ncbi.nlm.nih.gov/pubmed/34404809
http://dx.doi.org/10.1038/s41467-021-25277-0

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8371172/
https://www.ncbi.nlm.nih.gov/pubmed/34404809
http://dx.doi.org/10.1038/s41467-021-25277-0

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