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Correlations between ligand field Δ(o), spin crossover T(1/2) and redox potential E(pa) in a family of five dinuclear helicates

A family of five new bis-bidentate azole–triazole Rat ligands (1,3-bis(5-(azole)-4-isobutyl-4H-1,2,4-triazol-3-yl)benzene), varying in choice of azole (2-imidazole, 4-imidazole, 1-methyl-4-imidazole, 4-oxazole and 4-thiazole), and the corresponding family of spin-crossover (SCO) and redox active tri...

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Detalles Bibliográficos
Autores principales: Singh, Sandhya, Brooker, Sally
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8372313/
https://www.ncbi.nlm.nih.gov/pubmed/34447566
http://dx.doi.org/10.1039/d1sc01458g