Borane-catalyzed selective dihydrosilylation of terminal alkynes: reaction development and mechanistic insight

Here, we describe simple B(C(6)F(5))(3)-catalyzed mono- and dihydrosilylation reactions of terminal alkynes by using a silane-tuned chemoselectivity strategy, affording vinylsilanes and unsymmetrical geminal bis(silanes). This strategy is applicable to the dihydrosilylation of both aliphatic and ary...

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Detalles Bibliográficos
Autores principales: Wang, Guoqiang, Su, Xiaoshi, Gao, Liuzhou, Liu, Xueting, Li, Guoao, Li, Shuhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8372554/
https://www.ncbi.nlm.nih.gov/pubmed/34476068
http://dx.doi.org/10.1039/d1sc02769g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8372554/
https://www.ncbi.nlm.nih.gov/pubmed/34476068
http://dx.doi.org/10.1039/d1sc02769g

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