Palladium-catalyzed benzylic C(sp(3))–H carbonylative arylation of azaarylmethyl amines with aryl bromides

A highly selective palladium-catalyzed carbonylative arylation of weakly acidic benzylic C(sp(3))–H bonds of azaarylmethylamines with aryl bromides under 1 atm of CO gas has been achieved. This work represents the first examples of use of such weakly acidic pronucleophiles in this class of transform...

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Detalles Bibliográficos
Autores principales: Zhao, Haoqiang, Hu, Bowen, Xu, Lijin, Walsh, Patrick J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8372623/
https://www.ncbi.nlm.nih.gov/pubmed/34476065
http://dx.doi.org/10.1039/d1sc02078a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8372623/
https://www.ncbi.nlm.nih.gov/pubmed/34476065
http://dx.doi.org/10.1039/d1sc02078a

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