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Reversible Switching of Single-Molecule Magnetic Behaviour by Desorption/Adsorption of Solvent Ligand in a New Dy(III)-Based Metal Organic Framework

Two metal-organic frameworks (MOFs), [Dy(BDC)(NO(3))(DMF)(2)](n) (1, H(2)BDC = terephthalic acid) and [Dy(BDC)(NO(3))](n) (1a), were synthesized. The structures of MOFs 1 and 1a are easy to be reversibly transformed into each other by the desorption or adsorption of coordination solvent molecules. A...

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Detalles Bibliográficos
Autores principales: Song, Xiao-Jiao, Hu, Zhao-Bo, Li, Miao-Miao, Feng, Xin, Kong, Ming, Xue, Xiao-Ming, Zhang, Yi-Quan, Song, You
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8374150/
https://www.ncbi.nlm.nih.gov/pubmed/34422769
http://dx.doi.org/10.3389/fchem.2021.714851