Catalytic Hydrodefluorination via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers

[Image: see text] Herein, we report a hydrodefluorination reaction of polyfluoroarenes catalyzed by bismuthinidenes, Phebox-Bi(I) and OMe-Phebox-Bi(I). Mechanistic studies on the elementary steps support a Bi(I)/Bi(III) redox cycle that comprises C(sp(2))–F oxidative addition, F/H ligand metathesis,...

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Detalles Bibliográficos
Autores principales: Pang, Yue, Leutzsch, Markus, Nöthling, Nils, Katzenburg, Felix, Cornella, Josep
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8377712/
https://www.ncbi.nlm.nih.gov/pubmed/34358426
http://dx.doi.org/10.1021/jacs.1c06735

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8377712/
https://www.ncbi.nlm.nih.gov/pubmed/34358426
http://dx.doi.org/10.1021/jacs.1c06735

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