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Rhodium and Iridium Mediated C-H and O-H Bond Activation of Two Schiff Base Ligands: Synthesis, Characterization and Catalytic Properties of the Organometallic Complexes

Reaction of [Rh(PPh(3))(3)Cl] with two Schiff base ligands, viz. N-(2′-hydroxyphenyl)furan-2-aldimine (H (2) L (1)) and N-(2′-hydroxyphenyl)thiophene-2-aldimine (H (2) L (2)), in refluxing toluene affords organorhodium complexes of type [Rh(PPh(3))(2)(L)Cl] (L = L(1) and L(2)). Similar reaction with...

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Detalles Bibliográficos
Autores principales: Sengupta, Poulami, Das, Rituparna, Dhibar, Papu, Paul, Piyali, Bhattacharya, Samaresh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8380818/
https://www.ncbi.nlm.nih.gov/pubmed/34434917
http://dx.doi.org/10.3389/fchem.2021.696460