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Following in Emil Fischer’s Footsteps: A Site-Selective Probe of Glucose Acid–Base Chemistry

[Image: see text] Liquid-jet photoelectron spectroscopy was applied to determine the first acid dissociation constant (pK(a)) of aqueous-phase glucose while simultaneously identifying the spectroscopic signature of the respective deprotonation site. Valence spectra from solutions at pH values below...

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Detalles Bibliográficos
Autores principales: Malerz, Sebastian, Mudryk, Karen, Tomaník, Lukáš, Stemer, Dominik, Hergenhahn, Uwe, Buttersack, Tillmann, Trinter, Florian, Seidel, Robert, Quevedo, Wilson, Goy, Claudia, Wilkinson, Iain, Thürmer, Stephan, Slavíček, Petr, Winter, Bernd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8381351/
https://www.ncbi.nlm.nih.gov/pubmed/34328745
http://dx.doi.org/10.1021/acs.jpca.1c04695