Synthesis of a carborane-substituted bis(phosphanido) cobaltate(i), ligand substitution, and unusual P(4) fragmentation

Oxidative addition of the P–P single bond of an ortho-carborane-derived 1,2-diphosphetane (1,2-C(2)(PMes)(2)B(10)H(10)) (Mes = 2,4,6-Me(3)C(6)H(2)) to cobalt(−i) and nickel(0) sources affords the first heteroleptic complexes of a carborane-bridged bis(phosphanido) ligand. The complexes also incorpor...

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Detalles Bibliográficos
Autores principales: Coburger, Peter, Leitl, Julia, Scott, Daniel J., Hierlmeier, Gabriele, Shenderovich, Ilya G., Hey-Hawkins, Evamarie, Wolf, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8386647/
https://www.ncbi.nlm.nih.gov/pubmed/34522320
http://dx.doi.org/10.1039/d1sc02948g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8386647/
https://www.ncbi.nlm.nih.gov/pubmed/34522320
http://dx.doi.org/10.1039/d1sc02948g

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