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Synthesis of a carborane-substituted bis(phosphanido) cobaltate(i), ligand substitution, and unusual P(4) fragmentation
Oxidative addition of the P–P single bond of an ortho-carborane-derived 1,2-diphosphetane (1,2-C(2)(PMes)(2)B(10)H(10)) (Mes = 2,4,6-Me(3)C(6)H(2)) to cobalt(−i) and nickel(0) sources affords the first heteroleptic complexes of a carborane-bridged bis(phosphanido) ligand. The complexes also incorpor...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8386647/ https://www.ncbi.nlm.nih.gov/pubmed/34522320 http://dx.doi.org/10.1039/d1sc02948g |