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Force-modulated reductive elimination from platinum(ii) diaryl complexes

Coupled mechanical forces are known to drive a range of covalent chemical reactions, but the effect of mechanical force applied to a spectator ligand on transition metal reactivity is relatively unexplored. Here we quantify the rate of C(sp(2))–C(sp(2)) reductive elimination from platinum(ii) diaryl...

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Detalles Bibliográficos
Autores principales: Yu, Yichen, Wang, Chenxu, Wang, Liqi, Sun, Cai-Li, Boulatov, Roman, Widenhoefer, Ross A., Craig, Stephen L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8386663/
https://www.ncbi.nlm.nih.gov/pubmed/34522310
http://dx.doi.org/10.1039/d1sc03182a