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Theoretical Modeling (Sparkle RM1 and PM7) and Crystal Structures of the Luminescent Dinuclear Sm(III) and Eu(III) Complexes of 6,6,7,7,8,8,8- Heptafluoro-2,2-dimethyl-3,5-octanedione and 2,3-Bis(2-pyridyl)pyrazine: Determination of Individual Spectroscopic Parameters for Two Unique Eu(3+) Sites
[Image: see text] Heteroleptic homo dinuclear complexes [Sm(fod)(3)(μ-bpp)Sm(fod)(3)] and [Eu(fod)(3)(μ-bpp)Eu(fod)(3)] and their diamagnetic analogue [Lu(fod)(3)(μ-bpp)Lu(fod)(3)] (fod is the anion of 6,6,7,7,8,8,8- heptafluoro-2,2-dimethyl-3,5-octanedione (Hfod) and bpp is 2,3-bis(2-pyridyl)pyrazi...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8387994/ https://www.ncbi.nlm.nih.gov/pubmed/34471726 http://dx.doi.org/10.1021/acsomega.0c05976 |