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Theoretical Modeling (Sparkle RM1 and PM7) and Crystal Structures of the Luminescent Dinuclear Sm(III) and Eu(III) Complexes of 6,6,7,7,8,8,8- Heptafluoro-2,2-dimethyl-3,5-octanedione and 2,3-Bis(2-pyridyl)pyrazine: Determination of Individual Spectroscopic Parameters for Two Unique Eu(3+) Sites

[Image: see text] Heteroleptic homo dinuclear complexes [Sm(fod)(3)(μ-bpp)Sm(fod)(3)] and [Eu(fod)(3)(μ-bpp)Eu(fod)(3)] and their diamagnetic analogue [Lu(fod)(3)(μ-bpp)Lu(fod)(3)] (fod is the anion of 6,6,7,7,8,8,8- heptafluoro-2,2-dimethyl-3,5-octanedione (Hfod) and bpp is 2,3-bis(2-pyridyl)pyrazi...

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Detalles Bibliográficos
Autores principales: Ganaie, Aabid Bashir, Iftikhar, Khalid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8387994/
https://www.ncbi.nlm.nih.gov/pubmed/34471726
http://dx.doi.org/10.1021/acsomega.0c05976