Relativity as a Synthesis Design Principle: A Comparative Study of [3 + 2] Cycloaddition of Technetium(VII) and Rhenium(VII) Trioxo Complexes with Olefins

[Image: see text] The difference in [3 + 2] cycloaddition reactivity between fac-[MO(3)(tacn)](+) (M = Re, (99)Tc; tacn = 1,4,7-triazacyclononane) complexes has been reexamined with a selection of unsaturated substrates including sodium 4-vinylbenzenesulfonate, norbornene, 2-butyne, and 2-methyl-3-b...

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Detalles Bibliográficos
Autores principales: Braband, Henrik, Benz, Michael, Spingler, Bernhard, Conradie, Jeanet, Alberto, Roger, Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8388117/
https://www.ncbi.nlm.nih.gov/pubmed/34255507
http://dx.doi.org/10.1021/acs.inorgchem.1c00995

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8388117/
https://www.ncbi.nlm.nih.gov/pubmed/34255507
http://dx.doi.org/10.1021/acs.inorgchem.1c00995

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