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Relativity as a Synthesis Design Principle: A Comparative Study of [3 + 2] Cycloaddition of Technetium(VII) and Rhenium(VII) Trioxo Complexes with Olefins
[Image: see text] The difference in [3 + 2] cycloaddition reactivity between fac-[MO(3)(tacn)](+) (M = Re, (99)Tc; tacn = 1,4,7-triazacyclononane) complexes has been reexamined with a selection of unsaturated substrates including sodium 4-vinylbenzenesulfonate, norbornene, 2-butyne, and 2-methyl-3-b...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8388117/ https://www.ncbi.nlm.nih.gov/pubmed/34255507 http://dx.doi.org/10.1021/acs.inorgchem.1c00995 |