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Coordination of a Neutral Ligand to a Metal Center of Oxohalido Anions: Fact or Fiction?

[Image: see text] Can a neutral ligand bond to a metal center of a square pyramidal oxohalido anion at the available sixth octahedral position? Crystal structures of some compounds indeed suggest that ligands, such as THF, pyridine, H(2)O, NH(3), and CH(3)CN, can interact with the central metal atom...

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Detalles Bibliográficos
Autores principales: Kokalj, Anton, Zupanek, Žiga, Tramšek, Melita, Tavčar, Gašper
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8388118/
https://www.ncbi.nlm.nih.gov/pubmed/34350762
http://dx.doi.org/10.1021/acs.inorgchem.1c00947