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A Flexible Synthetic Strategy for the Preparation of Heteroleptic Metallacycles of Porphyrins

[Image: see text] We present a stepwise synthetic strategy for the preparation of the unprecedented heteroleptic 2+2 neutral metallacycle [{t,c,c-RuCl(2)(CO)(2)}(2)(4′cisDPyP)(3′cisDPyP)] (5), in which two different 5,10-meso-dipyridylporphyrins, 4′cisDPyP [i.e., 5,10-bis(4′-pyridyl)-15,20-diphenylp...

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Detalles Bibliográficos
Autores principales: Vidal, Alessio, Battistin, Federica, Balducci, Gabriele, Iengo, Elisabetta, Alessio, Enzo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8389808/
https://www.ncbi.nlm.nih.gov/pubmed/34264053
http://dx.doi.org/10.1021/acs.inorgchem.1c01511