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Metal–Micelle Cooperativity: Phosphine Ligand-Free Ultrasmall Palladium(II) Nanoparticles for Oxidative Mizoroki–Heck-type Couplings in Water at Room Temperature

[Image: see text] The amphiphile PS-750-M generates stable, phosphine ligand-free, and catalytically active ultrasmall Pd(II) nanoparticles (NPs) from Pd(OAc)(2), preventing their precipitation, polymerization, and oxidation state changes. PS-750-M directly interacts with Pd(II) NP surfaces, as conf...

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Detalles Bibliográficos
Autores principales: Ansari, Tharique N., Jasinski, Jacek B., Leahy, David K., Handa, Sachin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8395633/
https://www.ncbi.nlm.nih.gov/pubmed/34467295
http://dx.doi.org/10.1021/jacsau.0c00087