Cargando…
Probing the All-Ferrous States of Methanogen Nitrogenase Iron Proteins
[Image: see text] The Fe protein of nitrogenase reduces two C1 substrates, CO(2) and CO, under ambient conditions when its [Fe(4)S(4)] cluster adopts the all-ferrous [Fe(4)S(4)](0) state. Here, we show disparate reactivities of the nifH- and vnf-encoded Fe proteins from Methanosarcina acetivorans (d...
Autores principales: | , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8395668/ https://www.ncbi.nlm.nih.gov/pubmed/34467276 http://dx.doi.org/10.1021/jacsau.0c00072 |