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Probing the All-Ferrous States of Methanogen Nitrogenase Iron Proteins

[Image: see text] The Fe protein of nitrogenase reduces two C1 substrates, CO(2) and CO, under ambient conditions when its [Fe(4)S(4)] cluster adopts the all-ferrous [Fe(4)S(4)](0) state. Here, we show disparate reactivities of the nifH- and vnf-encoded Fe proteins from Methanosarcina acetivorans (d...

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Detalles Bibliográficos
Autores principales: Solomon, Joseph B., Rasekh, Mahtab F., Hiller, Caleb J., Lee, Chi Chung, Tanifuji, Kazuki, Ribbe, Markus W., Hu, Yilin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8395668/
https://www.ncbi.nlm.nih.gov/pubmed/34467276
http://dx.doi.org/10.1021/jacsau.0c00072