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Nanocatalysts for High Selectivity Enyne Cyclization: Oxidative Surface Reorganization of Gold Sub-2-nm Nanoparticle Networks

[Image: see text] Ultrasmall gold nanoparticles (NPs) stabilized in networks by polymantane ligands (diamondoids) were successfully used as precatalysts for highly selective heterogeneous gold-catalyzed dimethyl allyl(propargyl)malonate cyclization to 5-membered conjugated diene. Such reaction usual...

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Detalles Bibliográficos
Autores principales: Nasrallah, Houssein O., Min, Yuanyuan, Lerayer, Emmanuel, Nguyen, Tuan-Anh, Poinsot, Didier, Roger, Julien, Brandès, Stéphane, Heintz, Olivier, Roblin, Pierre, Jolibois, Franck, Poteau, Romuald, Coppel, Yannick, Kahn, Myrtil L., Gerber, Iann C., Axet, M. Rosa, Serp, Philippe, Hierso, Jean-Cyrille
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8395676/
https://www.ncbi.nlm.nih.gov/pubmed/34467283
http://dx.doi.org/10.1021/jacsau.0c00062