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New Magic Au(24) Cluster Stabilized by PVP: Selective Formation, Atomic Structure, and Oxidation Catalysis

[Image: see text] An unprecedented magic number cluster, Au(24)Cl(x) (x = 0–3), was selectively synthesized by the kinetically controlled reduction of the Au precursor ions in a microfluidic mixer in the presence of a large excess of poly(N-vinyl-2-pyrrolidone) (PVP). The atomic structure of the PVP...

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Detalles Bibliográficos
Autores principales: Hasegawa, Shingo, Takano, Shinjiro, Harano, Koji, Tsukuda, Tatsuya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8395683/
https://www.ncbi.nlm.nih.gov/pubmed/34467325
http://dx.doi.org/10.1021/jacsau.1c00102