Cargando…

The Carbene Cannibal: Photoinduced Symmetry-Breaking Charge Separation in an Fe(III) N-Heterocyclic Carbene

[Image: see text] Photoinduced symmetry-breaking charge separation (SB-CS) processes offer the possibility of harvesting solar energy by electron transfer between identical molecules. Here, we present the first case of direct observation of bimolecular SB-CS in a transition metal complex, [Fe(III)L(...

Descripción completa

Detalles Bibliográficos
Autores principales: Kaul, Nidhi, Lomoth, Reiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8397313/
https://www.ncbi.nlm.nih.gov/pubmed/34264638
http://dx.doi.org/10.1021/jacs.1c03770