Cargando…
The Carbene Cannibal: Photoinduced Symmetry-Breaking Charge Separation in an Fe(III) N-Heterocyclic Carbene
[Image: see text] Photoinduced symmetry-breaking charge separation (SB-CS) processes offer the possibility of harvesting solar energy by electron transfer between identical molecules. Here, we present the first case of direct observation of bimolecular SB-CS in a transition metal complex, [Fe(III)L(...
Autores principales: | Kaul, Nidhi, Lomoth, Reiner |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2021
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8397313/ https://www.ncbi.nlm.nih.gov/pubmed/34264638 http://dx.doi.org/10.1021/jacs.1c03770 |
Ejemplares similares
-
High-Efficiency Photoinduced
Charge Separation in
Fe(III)carbene Thin Films
por: Zhang, Minli, et al.
Publicado: (2023) -
Photoredox catalysis via consecutive (2)LMCT- and (3)MLCT-excitation of an Fe(iii/ii)–N-heterocyclic carbene complex
por: Ilic, Aleksandra, et al.
Publicado: (2022) -
N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?
por: Gehrke, Sascha, et al.
Publicado: (2020) -
N-Heterocyclic carbenes
por: Nolan, Steven P
Publicado: (2015) -
Competing dynamics of intramolecular deactivation and bimolecular charge transfer processes in luminescent Fe(iii) N-heterocyclic carbene complexes
por: Rosemann, Nils W., et al.
Publicado: (2023)