DFT Study on the Biosynthesis of Verrucosane Diterpenoids and Mangicol Sesterterpenoids: Involvement of Secondary-Carbocation-Free Reaction Cascades

[Image: see text] Some experimental observations indicate that a sequential formation of secondary (2°) carbocations might be involved in some biosynthetic pathways, including those of verrucosane-type diterpenoids and mangicol-type sesterterpenoids, but it remains controversial whether or not such...

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Detalles Bibliográficos
Autores principales: Sato, Hajime, Li, Bi-Xiao, Takagi, Taisei, Wang, Chao, Miyamoto, Kazunori, Uchiyama, Masanobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8397367/
https://www.ncbi.nlm.nih.gov/pubmed/34467361
http://dx.doi.org/10.1021/jacsau.1c00178

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8397367/
https://www.ncbi.nlm.nih.gov/pubmed/34467361
http://dx.doi.org/10.1021/jacsau.1c00178

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