Accelerating the insertion reactions of (NHC)Cu–H via remote ligand functionalization

Most ligand designs for reactions catalyzed by (NHC)Cu–H (NHC = N-heterocyclic carbene ligand) have focused on introducing steric bulk near the Cu center. Here, we evaluate the effect of remote ligand modification in a series of [(NHC)CuH](2) in which the para substituent (R) on the N-aryl groups of...

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Detalles Bibliográficos
Autores principales: Speelman, Amy L., Tran, Ba L., Erickson, Jeremy D., Vasiliu, Monica, Dixon, David A., Bullock, R. Morris
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8409461/
https://www.ncbi.nlm.nih.gov/pubmed/34567502
http://dx.doi.org/10.1039/d1sc01911b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8409461/
https://www.ncbi.nlm.nih.gov/pubmed/34567502
http://dx.doi.org/10.1039/d1sc01911b

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