Atom-efficient transition-metal-free arylation of N,O-acetals using diarylzinc reagents through Zn/Zn cooperativity

Exploiting the cooperative action of Lewis acid Zn(C(6)F(5))(2) with diarylzinc reagents, the efficient arylation of N,O-acetals to access diarylmethylamines is reported. Reactions take place under mild reaction conditions without the need for transtion-metal catalysis. Mechanistic investigations ha...

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Detalles Bibliográficos
Autores principales: Borys, Andryj M., Gil-Negrete, Jose M., Hevia, Eva
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8419782/
https://www.ncbi.nlm.nih.gov/pubmed/34486629
http://dx.doi.org/10.1039/d1cc04137a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8419782/
https://www.ncbi.nlm.nih.gov/pubmed/34486629
http://dx.doi.org/10.1039/d1cc04137a

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