Combined Experimental and Computational Study of Ruthenium N-Hydroxyphthalimidoyl Carbenes in Alkene Cyclopropanation Reactions

[Image: see text] A combined experimental–computational approach has been used to study the cyclopropanation reaction of N-hydroxyphthalimide diazoacetate (NHPI-DA) with various olefins, catalyzed by a ruthenium-phenyloxazoline (Ru-Pheox) complex. Kinetic studies show that the better selectivity of...

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Detalles Bibliográficos
Autores principales: Planas, Ferran, Costantini, Matteo, Montesinos-Magraner, Marc, Himo, Fahmi, Mendoza, Abraham
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8419840/
https://www.ncbi.nlm.nih.gov/pubmed/34504736
http://dx.doi.org/10.1021/acscatal.1c02540

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8419840/
https://www.ncbi.nlm.nih.gov/pubmed/34504736
http://dx.doi.org/10.1021/acscatal.1c02540

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