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Combined Experimental and Computational Study of Ruthenium N-Hydroxyphthalimidoyl Carbenes in Alkene Cyclopropanation Reactions
[Image: see text] A combined experimental–computational approach has been used to study the cyclopropanation reaction of N-hydroxyphthalimide diazoacetate (NHPI-DA) with various olefins, catalyzed by a ruthenium-phenyloxazoline (Ru-Pheox) complex. Kinetic studies show that the better selectivity of...
Autores principales: | Planas, Ferran, Costantini, Matteo, Montesinos-Magraner, Marc, Himo, Fahmi, Mendoza, Abraham |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8419840/ https://www.ncbi.nlm.nih.gov/pubmed/34504736 http://dx.doi.org/10.1021/acscatal.1c02540 |
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