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The Smallest Polyoxotungstate Retained by TRIS-Stabilization

[Image: see text] A polycondensation reaction of the orthotungstate anion WO(4)(2–), buffered at pH 7.5 in a TRIS-HCl (0.15 M) solution, results in the first example of a discrete polyoxotungstate anion, with just two W ions stabilized with TRIS ligands. It was isolated and characterized as Na(2)[W(...

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Detalles Bibliográficos
Autores principales: Gumerova, Nadiia I., Prado-Roller, Alexander, Rambaran, Mark A., Ohlin, C. André, Rompel, Annette
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8424642/
https://www.ncbi.nlm.nih.gov/pubmed/34121393
http://dx.doi.org/10.1021/acs.inorgchem.1c01188