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The Smallest Polyoxotungstate Retained by TRIS-Stabilization
[Image: see text] A polycondensation reaction of the orthotungstate anion WO(4)(2–), buffered at pH 7.5 in a TRIS-HCl (0.15 M) solution, results in the first example of a discrete polyoxotungstate anion, with just two W ions stabilized with TRIS ligands. It was isolated and characterized as Na(2)[W(...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8424642/ https://www.ncbi.nlm.nih.gov/pubmed/34121393 http://dx.doi.org/10.1021/acs.inorgchem.1c01188 |