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Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations

The delivery of alkyl radicals through photocatalytic deoxygenation of primary alcohols under mild conditions is a so far unmet challenge. In this report, we present a one-pot strategy for deoxygenative Giese reaction of alcohols with electron-deficient alkenes, by using xanthate salts as alcohol-ac...

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Detalles Bibliográficos
Autores principales: Guo, Hong-Mei, Wu, Xuesong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8433232/
https://www.ncbi.nlm.nih.gov/pubmed/34508098
http://dx.doi.org/10.1038/s41467-021-25702-4