A “Pretender” Croconate-Bridged Macrocyclic Tetraruthenium Complex: Sizable Redox Potential Splittings despite Electronically Insulated Divinylphenylene Diruthenium Entities

Careful optimization of the reaction conditions provided access to the particularly small tetraruthenium macrocycle (2)Ru(2)Ph-Croc, which is composed out of two redox-active divinylphenylene-bridged diruthenium entities {Ru}-1,4-CH=CH-C(6)H(4)-CH=CH-{Ru} (Ru(2)Ph; {Ru} = Ru(CO)Cl(P(i)Pr(3))(2)) and...

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Detalles Bibliográficos
Autores principales: Rotthowe, Nils, Linseis, Michael, Vogelsang, Lars, Orth, Nicole, Ivanović-Burmazović, Ivana, Winter, Rainer F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8433806/
https://www.ncbi.nlm.nih.gov/pubmed/34500666
http://dx.doi.org/10.3390/molecules26175232

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8433806/
https://www.ncbi.nlm.nih.gov/pubmed/34500666
http://dx.doi.org/10.3390/molecules26175232

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