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A “Pretender” Croconate-Bridged Macrocyclic Tetraruthenium Complex: Sizable Redox Potential Splittings despite Electronically Insulated Divinylphenylene Diruthenium Entities
Careful optimization of the reaction conditions provided access to the particularly small tetraruthenium macrocycle (2)Ru(2)Ph-Croc, which is composed out of two redox-active divinylphenylene-bridged diruthenium entities {Ru}-1,4-CH=CH-C(6)H(4)-CH=CH-{Ru} (Ru(2)Ph; {Ru} = Ru(CO)Cl(P(i)Pr(3))(2)) and...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8433806/ https://www.ncbi.nlm.nih.gov/pubmed/34500666 http://dx.doi.org/10.3390/molecules26175232 |