Efficient Direct Nitrosylation of α-Diimine Rhenium Tricarbonyl Complexes to Structurally Nearly Identical Higher Charge Congeners Activable towards Photo-CO Release

The reaction of rhenium α-diimine (N-N) tricarbonyl complexes with nitrosonium tetrafluoroborate yields the corresponding dicarbonyl-nitrosyl [Re(CO)(2)(NO)(N-N)X](+) species (where X = halide). The complexes, accessible in a single step in good yield, are structurally nearly identical higher charge...

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Detalles Bibliográficos
Autores principales: Nasiri Sovari, Sara, Kolly, Isabelle, Schindler, Kevin, Cortat, Youri, Liu, Shing-Chi, Crochet, Aurelien, Pavic, Aleksandar, Zobi, Fabio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8434269/
https://www.ncbi.nlm.nih.gov/pubmed/34500734
http://dx.doi.org/10.3390/molecules26175302

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8434269/
https://www.ncbi.nlm.nih.gov/pubmed/34500734
http://dx.doi.org/10.3390/molecules26175302

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