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Enantioselective vinylogous-Mukaiyama-type dearomatisation by anion-binding catalysis

The first enantioselective vinylogous Mukaiyama-type dearomatisation of heteroarenes under anion-binding catalysis is presented. A recyclable tetrakistriazole catalyst was used for the enantiocontrol of the remote vinylogous active position of silyl dienol ethers. This approach provided chiral heter...

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Detalles Bibliográficos
Autores principales: Kaur, Kirandeep, Humbrías-Martín, Jorge, Hoppmann, Leon, Fernández-Salas, Jose A., Daniliuc, Constantin G., Alemán, José, Mancheño, Olga García
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8438702/
https://www.ncbi.nlm.nih.gov/pubmed/34519302
http://dx.doi.org/10.1039/d1cc03514b